A pentiptycene-derived light-driven molecular brake.

نویسندگان

  • Jye-Shane Yang
  • Yao-Ting Huang
  • Jinn-Hsuan Ho
  • Wei-Ting Sun
  • Hsin-Hau Huang
  • Ying-Chih Lin
  • Shing-Jong Huang
  • Shou-Ling Huang
  • Hsiu-Feng Lu
  • Ito Chao
چکیده

A room-temperature light-driven molecular brake (1), consisting of a pentiptycene rotator, a 3,5-dinitrophenyl brake, and a photoisomerizable ethenyl spacer, is reported. The rotation rates of the rotator differ by about 9 orders of magnitude between the brake-on (cis-1) and brake-off (trans-1) states.

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عنوان ژورنال:
  • Organic letters

دوره 10 11  شماره 

صفحات  -

تاریخ انتشار 2008